;csaAmplification853 ;csaAmplification853 sequence ;Avance II+ version ;parameters: ;p3 : 1H 90 degree pulse length at power level pl22 ;pl22 : power level for 1H 90 degree pulse ;p15 : contact time ;pl1 : X power level for CP ;sp0 : H power level for CP ;p1 :13C 90 degree pulse length at power level pl11 ;p2 : 13C 180 degree pulse length at power level pl11 ;pl11 : power level for 13C pulses ;pl2 : =120dB, not used ;pl12 : decoupling power level ;pl13 : fslg decoupling power level ;d1 : relaxation delay ;cnst21 : on resonance, usually = 0 ;pcpd2 : pulse length for decoupling sequence ;cpdprg2 : decoupling (cw, tppm etc.) ;spnam0 : shape for CP ;zgoptns : -Dfslg, -Dlacq, or blank ;$COMMENT=CSA Amplification ;$CLASS=Solids ;$DIM=2D ;$TYPE=CSA measurement ;$SUBTYPE=Sideband ;$OWNER=JJT prosol relations= #include #ifdef fslg #include ;cnst20 : RF field achieved at pl13 ;cnst21 : on resonance, usually = 0 ;cnst22 : positive LG offset ;cnst23 : negative LG offset ;cnst24 : additional LG-offset #endif /* fslg */ ;cnst11 : to adjust t=0 for acquisition, if digmod = baseopt "acqt0=1u*cnst11" "d0=0.1u" "in0=inf1" "d21=0.25s/cnst31-(p2/2.0)" "d22=0.75s/cnst31-p2" "d23=0.5s/cnst31-p2" "d24=d23" "d25=d22" "d26=d21" "d27=d21-de" 1 ze 2 d1 do:f2 #include ;make sure p15 does not exceed 10 msec ;let supervisor change this pulseprogram if ;more is needed #ifndef lacq ;disable protection file for long acquisition change decoupling power !!! or you risk probe damage ;if you set the label lacq (ZGOPTNS -Dlacq), the protection is disabled #include ;allows max. 50 msec acquisition time, supervisor ;may change to max. 1s at less than 5 % duty cycle ;and reduced decoupling field #endif 1u fq=cnst21:f2 (p3 pl22 ph1):f2 (p15 pl1 ph2):f1 (p15:sp0 ph0):f2 d21 cpds2:f2 ;pl12 is used here with tppm, pl13 with cwlg, cwlgs (p2 pl11 ph3):f1 d22 (p2 pl11 ph4):f1 d23 (p2 pl11 ph5):f1 d24 (p2 pl11 ph4):f1 d25 (p2 pl11 ph3):f1 d26 (p1 pl11 ph6):f1 d0 do:f2 (p1 pl11 ph7):f1 d21 cpds2:f2 ;pl12 is used here with tppm, pl13 with cwlg, cwlgs (p2 pl11 ph13):f1 d22 (p2 pl11 ph14):f1 d23 (p2 pl11 ph15):f1 d24 (p2 pl11 ph14):f1 d25 (p2 pl11 ph13):f1 d27 go=2 ph31 1m do:f2 d1 mc #0 to 2 F1QF(id0) HaltAcqu, 1m exit ph0= 1 ph1= 0 2 ph2= 0 0 2 2 ph3= (12) 0 0 0 0 6 6 6 6 ph4= (12) 11 11 11 11 5 5 5 5 ph5= (12) 1 1 1 1 7 7 7 7 ph6= {1}*8 {2}*8 ph7= {0}*16 {2}*16 ph13= (12) {0}*32 {6}*32 ph14= (12) {11}*32 {5}*32 ph15= (12) {1}*32 {7}*32 ph31= 0 2 2 0 0 2 2 0 1 3 3 1 1 3 3 1 2 0 0 2 2 0 0 2 3 1 1 3 3 1 1 3